Coherent multidimensional spectroscopy has been widely used to investigate the ultrafast dynamics e.g. the coherence and the relaxation pathways in a wide range of samples. This technique has been well-established and proven useful  in NMR and IR region of the electromagnetic spectrum for decades and it's extension to Visible range is used to study the ultrafast dynamics especially coherences which persist for unexpectedly long time scale, in photosynthetic light-harvesting antennae.  These measurements are typically rely on using broadband ultra short pulses to explore the sample which allows many transitions and pathways to excite and contribute in the resultant spectra. Different contributing pathways can then be identified by inspecting the 2D maps that correlates the system dynamics at different inter-pulse time periods.   The first observations of coherence signals in 2D spectra of light-harvesting complexes, which persist for unexpectedly long time-scale, were taken as evidence for coherent superposition of electronic states, based on the the anti-correlated oscillation of the amplitude and diagonal width of the cross-peak in the 2D spectra both at cryogenic and ambient temperature, led to developing new theories beyond FORSTER of excitation energy transfer. However later on the nature of the observed features were questioned later on as similar behaviour was observed in monomeric dye solutions, which only exhibit vibrational coherences. This made the previous observations less fascinating as they could be the signature of vibrational modes of a single chromophore and thus, have no effect on the energy  transfer mechanism. Subsequently, several experimental techniques have been proposed and used in order to clarify the nature of the observed coherences in photosynthetic light-harvesting complexes such as using  rephasing and non-rephasing pulse ordering and specific polarization scheme and performing complementary measurements. There are, however, limitations and challenges to each of the proposed solutions that are exacerbated in systems such as light-harvesting complexes, where different pathways lead to signals that overlap in 2D spectra and multiple broad transitions are involved.  In such instances, the ability of femtosecond laser pulses to excite everything within their broad spectral bandwidth can become a limitation rather than a strength. some people used pathway selective..here we combine Here, we